64 research outputs found

    a resonant Raman study

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    We report resonant Raman scattering (RRS) by the TO, LO, and 2 LO modes of single wurtzite and zinc-blende GaAs nanowires. The optical band gap of wurtzite GaAs is 1.460eV ± 3meV at room temperature, and 35 ± 3meV larger than the GaAs zinc-blende band gap. Raman measurements using incoming light polarized parallel and perpendicular to the wire c axis allowed us to investigate the splitting of heavy Γ9 and light-hole Γ7 band at the Γ point of 65 ± 6meV

    a combined photoluminescence and resonant Raman scattering study

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    We used spatially resolved photoluminescence (PL) and resonant Raman spectroscopy to study the electronic structure of single GaAs nanowires (NWs) consisting of zinc-blende (ZB) and wurtzite (WZ) segments. For narrow ZB segments and stacking faults the energy range of the observed PL peak positions is found to deviate from that of the maxima in resonance Raman profiles. These different energy ranges reflect the fact that the PL recombination is dominated by spatially indirect transitions whereas the resonance enhancement of Raman scattering is caused by direct transitions. Our results provide evidence for the type II band alignment between ZB and WZ GaAs and a coherent picture of all near-band-gap transition energies in GaAs NWs
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